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All 3 posts Subject: Oxidation of Amines using Benzoyl peroxide Please login to post Down

pHarmacist
(Hive Addict)
05-11-03 20:19
No 432676
User Picture       Oxidation of Amines using Benzoyl peroxide

Improved Oxidation of Amines with Dibenzoyl Peroxide

Full-text: http://pharmacist8.tripod.com/OH-amines.pdf

Barium wink

Accept No Imitations, There Can Only Bee One; www.the-hive.ws

pHarmacist
(Hive Addict)
05-11-03 20:56
No 432681
User Picture       FLEA

Shulgin prepares FLEA from MDOH, now, it can also effectively bee prepared from MDMA.

See: http://www.erowid.org/library/books_online/pihkal/pihkal081.shtml

Accept No Imitations, There Can Only Bee One; www.the-hive.ws

obia
(Newbee)
05-12-03 21:23
No 432851
      noh amines from amines

from memory there is also a series of papers by Beckett which describe the oxidation of primary and secondary amines to the corresponding azanol. his method uses MCPBA metachloroperbenzoic acid followed by hydrolysis. unfortunately all these oxidation routes require preparation of the illegal amine and if you are going to prepare the amine why not just stop there and eat it, flea is not as interesting as its amine parent.
what is really needed is a route to produce an O substituted oxime (or perhaps a N-substituted nitrone) reduce to the o/n substituted hydroxyamine and then remove the o protection. at least that way if the reduction proceeds too far you don't end up with an illegal amine.

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	All 3 posts		Subject: Oxidation of Amines using Benzoyl peroxide		Please login to post		Down


		pHarmacist (Hive Addict) 05-11-03 20:19 No 432676				Oxidation of Amines using Benzoyl peroxide
						Improved Oxidation of Amines with Dibenzoyl Peroxide Full-text: http://pharmacist8.tripod.com/OH-amines.pdf Barium Accept No Imitations, There Can Only Bee One; www.the-hive.ws



		pHarmacist (Hive Addict) 05-11-03 20:56 No 432681				FLEA
						Shulgin prepares FLEA from MDOH, now, it can also effectively bee prepared from MDMA. See: http://www.erowid.org/library/books_online/pihkal/pihkal081.shtml Accept No Imitations, There Can Only Bee One; www.the-hive.ws



		obia (Newbee) 05-12-03 21:23 No 432851				noh amines from amines
						from memory there is also a series of papers by Beckett which describe the oxidation of primary and secondary amines to the corresponding azanol. his method uses MCPBA metachloroperbenzoic acid followed by hydrolysis. unfortunately all these oxidation routes require preparation of the illegal amine and if you are going to prepare the amine why not just stop there and eat it, flea is not as interesting as its amine parent. what is really needed is a route to produce an O substituted oxime (or perhaps a N-substituted nitrone) reduce to the o/n substituted hydroxyamine and then remove the o protection. at least that way if the reduction proceeds too far you don't end up with an illegal amine.

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