Main Index   Search   Register   Login   Who's Online   FAQ   Links
  1 Online, 0 Active   You are not logged in  
Main Index     The HIVE light edition (TM)
This is a historical archive
The forum is read-only. Private information has been removed. It is not possible to login.


Novel Discourse  

All 2 posts   Subject: A very comprehensive Nef Reaction Review   Please login to post   Down

 
    Rhodium
(Chief Bee)
04-09-04 01:32
No 499825
User Picture 
      A very comprehensive Nef Reaction Review
(Rated as: excellent)
    

Tetrahedron report number 667
Recent synthetic developments in the nitro to carbonyl conversion (Nef reaction)

Roberto Ballini and Marino Petrini
Tetrahedron 60(5), 1017-1047 (2004) (https://www.rhodium.ws/pdf/nef.reaction.review.2004.pdf)
DOI:10.1016/j.tet.2003.11.016 

nef.gif

Abstract
New synthetic approaches and applications of the Nef reaction, appeared in the literature since 1990, are reviewed.

The Hive - Clandestine Chemists Without Borders
 
 
 
 
    Rhodium
(Chief Bee)
10-22-04 00:49
No 537051
User Picture 
      Transformation of Aromatic Nitroalkanes into...
(Rated as: good read)
    

Transformation of Aromatic Nitroalkanes into Carbonyl Compounds by the Improved Nef Reaction
H. Chikashita, Y. Morita, and K. Itoh
Synth. Commun. 17(6), 677-683 (1987) (https://www.rhodium.ws/chemistry/nef.two-phase.html)



Abstract
An improved two-layer method of the Nef reaction which is effective for the conversion of a variety of aromatic nitroalkanes into carbonyl compounds is described.
The yields of phenylacetaldehydes from phenyl-2-nitroethanes cluster around 65% while phenylacetone is isolated in almost 90% yield, as are several related benzyl ketones..

The Hive - Clandestine Chemists Without Borders
 
 

All 2 posts   End of thread   Top
   

 https://the-hive.archive.erowid.org    the-hive@erowid.org
   
Powdered by Goatskin Lampshades® Release 5.01, 2013 - 2014, Chemhacks of Honey Unlimited International

Links     Erowid     Rhodium

PIHKAL     TIHKAL     Total Synthesis II

Date: 05-07-24, Release: 1.6 (10-04-15), Links: static, unique