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All 2 posts Subject: IBX Esters with Bleach! Please login to post Down

metanoid
(Stranger)
07-20-04 07:39
No 520388
      IBX Esters with Bleach!
(Rated as: excellent)

this is fantastic!

step 1. turn a 2-iodobenzoic acid ester into the corresponding ibx ester with bleach

step 2. benzyl alcohol -> benzaldehyde 100%

step 3. lots and lots of other oxidations.

here are the gooodies.

Rhodium
(Chief Bee)
08-13-04 02:57
No 525173
User Picture       Preparation of 2-iodoxybenzoate (IBX) esters
(Rated as: excellent)

Preparation and structure of 2-iodoxybenzoate esters: soluble and stable periodinane oxidizing reagents
V.V. Zhdankin, D.N. Litvinov, A.Y. Koposov, T. Luu, M.J. Ferguson, R. McDonald, R.R. Tykwinski
Chem. Commun.,(1), 106-107 (2004), DOI:10.1039/b312961f

Abstract
Esters of 2-iodoxybenzoic acid (IBX-esters) are potentially valuable oxidizing reagents belonging to a new class of pentavalent iodine compounds with a pseudo benziodoxole structure.

Full Text:

Supplementary Data (Microsoft Word format, 117 KB): Synthetic and characterization data for all new compounds (http://www.rsc.org/suppdata/cc/b3/b312961f/b312961f.doc)

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	All 2 posts		Subject: IBX Esters with Bleach!		Please login to post		Down


		metanoid (Stranger) 07-20-04 07:39 No 520388				IBX Esters with Bleach! (Rated as: excellent)
						this is fantastic! step 1. turn a 2-iodobenzoic acid ester into the corresponding ibx ester with bleach step 2. benzyl alcohol -> benzaldehyde 100% step 3. lots and lots of other oxidations. here are the gooodies.



		Rhodium (Chief Bee) 08-13-04 02:57 No 525173				Preparation of 2-iodoxybenzoate (IBX) esters (Rated as: excellent)
						Preparation and structure of 2-iodoxybenzoate esters: soluble and stable periodinane oxidizing reagents V.V. Zhdankin, D.N. Litvinov, A.Y. Koposov, T. Luu, M.J. Ferguson, R. McDonald, R.R. Tykwinski Chem. Commun.,(1), 106-107 (2004), DOI:10.1039/b312961f Abstract Esters of 2-iodoxybenzoic acid (IBX-esters) are potentially valuable oxidizing reagents belonging to a new class of pentavalent iodine compounds with a pseudo benziodoxole structure. Full Text: Supplementary Data (Microsoft Word format, 117 KB): Synthetic and characterization data for all new compounds (http://www.rsc.org/suppdata/cc/b3/b312961f/b312961f.doc) ^{The Hive - Clandestine Chemists Without Borders}

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